Poly[tetrakis(2,2′-bipyridine)undeca-μ-oxido-hexaoxidodicopper(II)hexavanadium(V)]
نویسندگان
چکیده
In the title organic-inorganic hybrid vanadate complex, [Cu(2)V(6)O(17)(C(10)H(8)N(2))(4)](n), the Cu(II) atom is six-coordinated by two chelating 2,2'-bipyridine (bipy) ligands and two vanadate O atoms in a distorted octa-hedral geometry. Two [Cu(bipy)(2)V(3)O(8)] units are linked by a bridging O atom, which lies on an inversion center, forming a dimeric unit. The dimeric units are further connected by bridging vanadate O atoms into a two-dimensional layer parallel to (100). The layers are connected by weak C-H⋯O hydrogen bonds.
منابع مشابه
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